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Discussion Forums - The Hendrix Group
HomeHomeDiscussionsDiscussionsGeneral Corrosi...General Corrosi...Weld Corrosion in 2 year old A312 TP316LWeld Corrosion in 2 year old A312 TP316L
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11/7/2004 9:00 AM
 
[updated:LAST EDITED ON Nov-07-04 AT 08:39 PM (CDT)]Gentlemen, I am working in a relitavly new CCGT i have noticed that we are experiencing weld corrosion on our sea water cooling pipes, i have asked the chemist for the cloridecontent of the sea water, but he only seems to be able to give me the salinity, is there a direct corrolation? Also after only 2 years of operation we now have one weld failure, and several others that look close, (we are currently doing a full survey) we also use Chlorine for shock & continuous dosing to inhibit marine growth, the sea temp is around 25 degrees C (taken at cooler inlets) The seawater is taken from a harbour through a sea well, not from a offshore pipe. The pipe class is CC.07 Material A312 TP316L Dn 20 Schd 40S I can supply any other info as i get it (still waiting for chemist report on sea water) i did a Dyp pen test on one weld, and the problem manifests its self as pin pricks, hope this may help Any comments please feel free Regards Eng Michael Jubb
 
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11/8/2004 9:00 AM
 
There are a lot of factors here. The chlorides are the big enemy of stainless steel and can cause corrosion of the welds quite easily. Was the unit passivated or electropolished before use (or both)? The weld area in the heat affected zone is a totally different kind of steel from the rest of it and is very prone to corrosion unless passivated or polished and passivated. Even then it will still be the weakest link on the 316L part. The worst condition is if it is exposed to sea water sporatically. In other words, if you alternatively expose it to sea water and air.
 
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11/8/2004 9:00 AM
 
In Reply: No the System in question is 100% duty. What i don't understand is not every weld is effected, it seems very random, During the next outage, i may cut a section and send it for anaysis, also it would be good to find a suitable weld proceedure for this application. Maybe Mr Hendrix & Co could advise on this? it would be VERY useful to have an approved 'weld spec' service on this website! If i can prove the weld spec has not been followed i may have a claim against the contractor. If we have to re-weld all the effected joints, what is the proceedure for local on site passivation?
 
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11/9/2004 9:00 AM
 
mickjubb: People do use 316LSS in seawater service, but successful use is tricky. Several corrosive mechanisms can come into play, including chloride pitting and MIC. Deposits also can contribute to localized corrosion. If the pitting is confined to welds, it is possible that heat tint from the welding is reducing the corrosion resistance in those areas. Heat tint will reduce the effective chromium content of the base metal, even with low-grade carbon content SS, and will lower the corrosion resistance. All heat tint should be removed from the welds and HAZ. The introduction of oxygen increases the aggressiveness of seawater and should be eliminated. The successful use of the 300-series grades of stainless steel in seawater also depends on maintaining adequate seawater velocities (>3 ft/sec.) and no stagnent environements (from shut-ins, etc.). P.S. The chloride content of seawater is %7E30,000 ppm, consisting primarily of sodium chloride with less quantities of calcium and magnesium chlorides. Hope this helps! David Hendrix The Hendrix Group Inc.
 
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11/9/2004 9:00 AM
 
Yes, Thank You Mr Hendrix The main question still has to be what to do about it!? and how do you remove heat tint from weld in the ID of a pipe 10M or so from the nearest flange? Regards Mick
 
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